Invention of MK-8262, a Cholesteryl Ester Transfer Protein (CETP) Inhibitor Backup to Anacetrapib with Best-in-Class Properties

J Med Chem. 2021 Sep 23;64(18):13215-13258. doi: 10.1021/acs.jmedchem.1c00959. Epub 2021 Aug 10.

Abstract

Cholesteryl ester transfer protein (CETP) represents one of the key regulators of the homeostasis of lipid particles, including high-density lipoprotein (HDL) and low-density lipoprotein (LDL) particles. Epidemiological evidence correlates increased HDL and decreased LDL to coronary heart disease (CHD) risk reduction. This relationship is consistent with a clinical outcomes trial of a CETP inhibitor (anacetrapib) combined with standard of care (statin), which led to a 9% additional risk reduction compared to standard of care alone. We discuss here the discovery of MK-8262, a CETP inhibitor with the potential for being the best-in-class molecule. Novel in vitro and in vivo paradigms were integrated to drug discovery to guide optimization informed by a critical understanding of key clinical adverse effect profiles. We present preclinical and clinical evidence of MK-8262 safety and efficacy by means of HDL increase and LDL reduction as biomarkers for reduced CHD risk.

MeSH terms

  • Animals
  • Anticholesteremic Agents / chemical synthesis
  • Anticholesteremic Agents / pharmacokinetics
  • Anticholesteremic Agents / therapeutic use*
  • Anticholesteremic Agents / toxicity
  • Cholesterol Ester Transfer Proteins / antagonists & inhibitors*
  • Coronary Disease / drug therapy*
  • Dogs
  • Humans
  • Macaca mulatta
  • Mice
  • Mice, Inbred C57BL
  • Molecular Structure
  • Oxazolidinones / chemical synthesis
  • Oxazolidinones / pharmacokinetics
  • Oxazolidinones / therapeutic use*
  • Oxazolidinones / toxicity
  • Rats
  • Rats, Wistar
  • Structure-Activity Relationship

Substances

  • Anticholesteremic Agents
  • CETP protein, human
  • Cholesterol Ester Transfer Proteins
  • Oxazolidinones
  • anacetrapib