Simultaneous adsorption and oxidation of Sb(III) from water by the pH-sensitive superabsorbent polymer hydrogel incorporated with Fe-Mn binary oxides composite

In this work, the superabsorbent polymer hydrogel (SPH) of Poly(potassium acrylate-co-acrylamide (PPAA)) incorporated with Fe-Mn binary oxides (FMBOs) was synthesized and used for the removal of Sb(III) from water. Characterization analysis proved that FMBO₃ was successfully encapsulated into the SPH. The Fe/Mn oxide species in the composite SPH comprised FeO(OH), Fe₂O₃, MnO(OH), and MnO₂. The functional groups including N-H, -OH, carboxy as well as Fe atoms were confirmed adsorption sites through ligand exchange and inner-sphere complexes formation. Mn oxides can partially oxidize Sb(III) to Sb(V). Compared with the pseudo-first-order model, the pseudo-second-order model could better describe the adsorption kinetics. And the swelling degree of the composite SPH had a positive impact on the removal rate. The Langmuir-Freundlich model was the most suitable isotherm model to analyze the experimental data. According to thermodynamic parameters, the adsorption process was a spontaneous exothermic reaction. The maximum adsorption capacity of the composite SPH for Sb(III) could be up to 105.59 mg/g at 288 K. In addition, a stable removal rate can be achieved over a wide pH range of 3-10, with little metal leaching even under acidic conditions. Furthermore, coexisting ions and DOM displayed an insignificant influence on the adsorption of Sb(III).