Considerations on Temperature Dependent Effective Diffusion and Permeability of Natural Clays

A series of porous clay samples prepared at different pretreatment temperatures have been tested in a diffusion chamber. Diffusivity and permeability were examined in a temperature range from ambient to 900 °C. Gaseous mixtures of O₂, CO₂, and N₂ have been applied, as these species are the relevant gases in the context of clay brick firing and similar thermochemical processes. Diffusive transport characteristics have been determined by means of the mean transport-pore model, and permeability has been evaluated by Darcy's law. CO₂ diffusivity increased strongly with temperature, whereas O₂ diffusion was limited to a certain level. It is proposed that one should consider CO₂ surface diffusion in order to explain this phenomenon. The diffusion model was expanded and surface diffusion was included in the model equation. The results of the model fit reflected the important role of incorporated carbonates of the clay foundation in gas-phase (molecular or Knudsen) diffusivity. CO₂ surface diffusion was observed to exhibit similar coefficients for two different investigated clays, and is therefore indicated as a property of natural clays. Permeability showed a progressive rise with temperature, in line with related literature.