Architecting an indirect Z-scheme NiCo₂O₄@CdS-Ag photocatalytic system with enhanced charge transfer for high-efficiency degradation of emerging pollutants

Bimetallic oxides with spinel structure show great prospects in the photocatalysis owing to many active sites. Herein, a novel 500NiCo₂O₄@CdS-5%Ag composite was fabricated via a feasible strategy. Interestingly, the combination with NiCo₂O₄ could significantly enhance the absorption ability of CdS for visible light. Benefiting from the formation of heterojunction structure between NiCo₂O₄ and CdS, the recombination of photogenerated electrons and holes was remarkably restrained. As an effective mediator, deposition of Ag could further promote the transfer of photogenerated charge carriers, thereby accelerating the reaction rate. Meanwhile, light absorption capacity of composite was also improved, owing to the surface plasmon resonance effect of metallic Ag. More importantly, 500NiCo₂O₄@CdS-5%Ag composite with great stability displayed an excellent performance in the photocatalytic degradation of OFX, and its highest removal efficiency was as high as 99.14%. Possible degradation pathways of OFX were given, and most of OFX could be degraded into CO₂, H₂O and other by-products with no toxicity. Significantly, the separation and transfer of photogenerated charge carriers followed indirect Z-scheme heterojunction mechanism. The O₂^-, OH and ¹O₂ were main active species in photocatalytic reaction system. All in all, current work inspired some new ideas for designing novel photocatalytic system in wastewater treatment.