In Situ Prepared NRCPFs as Highly Active Photo Platforms for in Situ Bond Formation Between Aryldiazonium Salts and Heteroarenes

Satyam Singh; Rajesh Kumar Yadav; Tae Wu Kim; Chandani Singh; Pooja Singh; Surabhi Chaubey; Baimuratova Rose; Dzhardimalieva Gulzhian; Prateek Khare

doi:10.1111/php.13639

In Situ Prepared NRCPFs as Highly Active Photo Platforms for in Situ Bond Formation Between Aryldiazonium Salts and Heteroarenes

Photochem Photobiol. 2022 Jul;98(4):748-753. doi: 10.1111/php.13639. Epub 2022 Jun 12.

Authors

Satyam Singh¹, Rajesh Kumar Yadav¹, Tae Wu Kim^{2

3}, Chandani Singh¹, Pooja Singh¹, Surabhi Chaubey¹, Baimuratova Rose⁴, Dzhardimalieva Gulzhian⁴, Prateek Khare⁵

Affiliations

¹ Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, India.
² Department of Chemistry, Mokpo National University, Muan-gun, Korea.
³ Spectrochemical Analysis Center for Organic & Inorganic Materials and Natural Products, Mokpo National University, Muan-gun, Korea.
⁴ Institute of Problems of Chemical Physics of RAS, Chernogolovka, Russia.
⁵ Department of Chemical Engineering, M.M.M. University of Technology, Gorakhpur, India.

PMID: 35502580
DOI: 10.1111/php.13639

Abstract

Covalent perylene frameworks (CPFs) with melamine linkages have newly received rising interest for a variety of applications because of nitrogen-rich content and high stability. Herein, we account a new simple strategy to in situ attain nitrogen-rich covalent perylene frameworks (NRCPFs) as highly active photo platforms for in situ bond formation between aryldiazonium salts and heteroarenes (C-H bond arylation) through the controlled photoredox route.