Immobilization on anionic metal(loid)s in soil by biochar: A meta-analysis assisted by machine learning

Metal pollution in soil has become one of the most serious environmental problems in China. Biochar is one of the most widely used remediation agents for soil metal pollution. However, the literature does not provide a consistent picture of the performance of biochar on the immobilization of anionic metal(loid)s, especially arsenic, in soil. To obtain a baseline understanding on the interactions of metals and biochar, 597 data records on four metal(loid)s (As, Cr, Sb and V) were collected from 70 publications for this meta-analysis, and the results are highlighted below. Biochar has a significant immobilization effect on anionic metal(loid)s in soil and reduces the bioavailability of these metals to plants. Subgroup analysis found that biochar could decrease the potential mobility of Cr, Sb and V, but the immobilization effect on As was not always consistent. Meanwhile, biochar pH and soil pH are the most key factors affecting the immobilization effect. To summarize, biochar can effectively immobilize Cr, Sb and V in soil, but more attention should be given to As immobilization in future applications. By regulating the properties of biochar and appropriate modification, anionic metal(loid)s in soil can be immobilized more effectively. Hence, both of the soil quality and crop quality can be improved.