Recent progress of photocatalysts based on tungsten and related metals for nitrogen reduction to ammonia

Photocatalytic nitrogen reduction reaction (NRR) to ammonia holds a great promise for substituting the traditional energy-intensive Haber-Bosch process, which entails sunlight as an inexhaustible resource and water as a hydrogen source under mild conditions. Remarkable progress has been achieved regarding the activation and solar conversion of N₂ to NH₃ with the rapid development of emerging photocatalysts, but it still suffers from low efficiency. A comprehensive review on photocatalysts covering tungsten and related metals as well as their broad ranges of alloys and compounds is lacking. This article aims to summarize recent advances in this regard, focusing on the strategies to enhance the photocatalytic performance of tungsten and related metal semiconductors for the NRR. The fundamentals of solar-to-NH₃ photocatalysis, reaction pathways, and NH₃ quantification methods are presented, and the concomitant challenges are also revealed. Finally, we cast insights into the future development of sustainable NH₃ production, and highlight some potential directions for further research in this vibrant field.