Fluorescent Talarolactones from Talaromyces sp

Chem Biodivers. 2022 Oct;19(10):e202200645. doi: 10.1002/cbdv.202200645. Epub 2022 Oct 5.

Abstract

(+)-Talarolactone C (1), Talarolactone A (2), Talarolactone B (3, sulfoxide derivative), and Talarolactone D (4, sulfone derivative) were isolated from Talaromyces sp. which was cultured in rice medium with sodium butyrate. The structures of talarolactone analogs above were characterized by a combination of spectroscopic, X-ray crystallographic, and computational methods. These talarolactones and Talarolactone A sodium (5) with the same carbon skeleton showed different fluorescence characteristics.

Keywords: Talarolactone; Talaromyces; fluorescence; structure elucidation.

MeSH terms

  • Butyric Acid
  • Carbon
  • Molecular Structure
  • Sodium
  • Sulfones
  • Sulfoxides
  • Talaromyces* / chemistry

Substances

  • Butyric Acid
  • Sulfones
  • Sulfoxides
  • Sodium
  • Carbon