A core/shell TiO₂ magnetized molecularly imprinted photocatalyst (MMIP@TiO₂): synthesis and its photodegradation activity towards sulfasalazine

Although the selectivity of TiO₂ for the degradation of target molecules is not enough, it is a broadly employed photocatalyst for the degradation of many pollutants. Molecularly imprinted compounds owing to their extreme recognition specificity have become increasingly popular for preparing selective photocatalysts. In this work, based on molecularly imprinted magnetized TiO₂ (MMIP@TiO₂), a selective photocatalyst was prepared. Via the co-precipitation method, Fe₃O₄ particles were prepared and coated respectively by SiO₂, vinyl end groups, and molecularly imprinted polymers (MIP). The synthesized photocatalyst was characterized by the X-ray diffraction method (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), energy-dispersive x-ray spectrometry (EDX), vibrating sample magnetometry (VSM), high-performance liquid chromatography (HPLC), and photoluminescence analysis (PL). The photocatalyst was then used to degrade the sulfasalazine pharmaceutical pollutant under UV irradiation. An average crystallite size of 9 nm was obtained for the MMIP@TiO₂ sample from the Scherrer formula and 34.5 nm by the Williamson-Hall formula. The results revealed that compared to the non-imprinted counterpart, the molecularly imprinted photocatalyst had significantly higher efficiency and selectivity for the degradation of target molecules. The process was forwarded with 90% efficiency within 10 min. Optimal conditions were 10.0 min irradiation when 25 mL SSZ solution (50 mg/L), 0.07 g/L catalyst dose, and pH 6.0 were applied. The maximum removal efficiency was calculated to be 92%. The external magnetic field quickly removed the photocatalyst from the solution and regenerated it. It was revealed that after each regeneration cycle, the efficiency dropped. Nevertheless, 63% of the preliminary effectiveness remained after four regeneration steps.