Amine-Functionalized Black Phosphorus Nanosheets toward Ultrafast and Room-Temperature Trace Carbon Dioxide Sensing

J Phys Chem Lett. 2022 Oct 20;13(41):9599-9606. doi: 10.1021/acs.jpclett.2c02788. Epub 2022 Oct 7.

Abstract

Carbon dioxide (CO2) poses a significant effect on global climate, indoor activity, and crop yield, thus necessitating real-time and high-performance detection. Traditional CO2-sensing materials always suffer from weak and sluggish reaction, elevated operation temperature, and poor detection limit. To surmount these obstacles, in this work a series of amine-rich polymer functionalized black phosphorus nanosheets (BP) were prepared for room-temperature CO2 detection. Superior to TMMAP or 3-DEAPTES modified counterparts, the BP-10% APTES sensor delivered a response of 28.5% and ultrafast response/recovery time of 4.7 s/4.8 s toward 10 ppm of CO2 under 36% RH at 22 °C, a lowest detection limit of 5 ppm, as well as excellent selectivity. Also, a nice repeatability and long-term operation stability were demonstrated. Thus, BP-APTES composites offer a promising strategy for high-performance CO2 detection in terms of high sensitivity, low power-consumption, and convenient fabrication, and showcase brilliant prospects in portable optoelectronic detection systems and the Internet of Things.