5f covalency from x-ray resonant Raman spectroscopy

X-ray resonant Raman spectroscopy (XRRS), a variant of resonant inelastic x-ray scattering, has been used to investigate the two prototype systems, UF₄and UO₂. Both are U5f²and each is an example of 5f localized, ionic behavior and 5f localized, covalent behavior, respectively. From the M₅XRRS measurements, the 5f band gap in each can be directly determined and, moreover, a clear and powerful sensitivity to 5f covalency emerges.