Phase Equilibria in Ternary System CsBr-AgBr-InBr₃

The double perovskite halides A₂B^IB^IIIX₆ provide flexibility for various formulation adjustments and are of less toxicity in comparison with well-discussed complex lead halide derivatives. Such type of structure can be formed by replacing two Pb²⁺ ions in the cubic lattice with a pair of non-toxic heterovalent (monovalent and trivalent) metal cations, such as silver and indium. The aim of this work is to briefly characterize the phase equilibria in the ternary system CsBr-AgBr-InBr₃ and investigate the thermodynamic availability of synthesis of Cs₂AgInBr₆ double perovskite phase by solid-state sintering or melt crystallization. The results demonstrate the unfeasibility of the Cs₂AgInBr₆ phase but high stability of the corresponding binary bromides perspective for optoelectronics.