Engineering work functions of cobalt-doped manganese oxide based electrocatalysts for highly efficient oxygen evolution reaction

The crystalline and electronic structures are two important factors for the design of electrocatalysts. In this work, Co-doped MnO electrocatalysts grown on nickel foam (NF) were prepared by a facile hydrothermal reaction, followed by H₂ treatment process. The electrocatalytic performance of MnO was significantly improved after doping with Co and the Co_0.1Mn_0.9O-NF sample achieved excellent oxygen evolution reaction (OER) performance with low overpotential (370 mV at 10 mA cm^-2) and reasonable Tafel slope (85.6 mV dec^-1). Significantly, the low work function was obtained in the Co_0.1Mn_0.9O-NF sample (4.37 eV), which could accelerate the charge transfer process of the OER activity. The excellent OER performance of the Co_0.1Mn_0.9O-NF sample is also attributed to the rich active sites, which improved electrical conductivity and enlarged electrochemical surface areas.