Characterization of structure-function properties relevant to copper-activated pyrite depression by different starches

Starches can adsorb on and depress copper-activated pyrite desirably during flotation, an important process in ore mineral extraction. In order to develop structure/function relationships, adsorption on and depression properties of copper-activated pyrite at pH 9 by normal wheat starch (NWS) and high-amylose wheat starch (HAW), dextrin, and a range of oxidized normal wheat starches (peroxide and hypochlorite treated) were investigated. Adsorption isotherms and bench flotation performance were compared with kinematic viscosity, molar mass distribution, surface coverage, and substituted functional groups assay. The differences in molar mass distribution and substituted functional groups among oxidized starches had little influence on the depression of copper-activated pyrite. However, the introduction of -C=O and -COOH substituents, combined with depolymerization, improved solubility and dispersibility, reduced aggregated structures, and strengthened surface binding of oxidized polymers, compared with NWS and HAW. At high concentrations, HAW, NWS, and dextrin were adsorbed onto the pyrite surface more than oxidized starches. However, at the low concentrations of depressant used in flotation, oxidized starches were more effective at selectively masking copper sites. This study suggests that a stable chelation between Cu(I) and starch ligands is necessary for depression of copper-activated pyrite at pH 9, which can be achieved with oxidized wheat starch.