Synthesis, Structures, and Magnetism of Four One-Dimensional Complexes Using [Ni(CN)₄]^2- and Macrocyclic Metal Complexes

Four one-dimensional complexes, denoted as [NiL₁][Ni(CN)₄] (1), [CuL₁][Ni(CN)₄] (2), [NiL₂][Ni(CN)₄]·2H₂O (3), and [CuL₂][Ni(CN)₄]·2H₂O (4) (L₁ = 1,8-dimethyl-1,3,6,8,10,13-hexaaza-cyclotetradecane; L₂ = 1,8-dipropyl-1,3,6,8,10,13-hexaazacyclotetradecane) were synthesized by reacting nickel/copper macrocyclic complexes with K₂[Ni(CN)₄]. Subsequently, the synthesized complexes were characterized using elemental analysis, infrared spectroscopy analysis, thermogravimetric analysis, and X-ray powder diffraction. Single-crystal structure analysis revealed that the Ni(II)/Cu(II) atoms were coordinated by two nitrogen atoms from [Ni(CN)₄]^2- with four nitrogen atoms from a macrocyclic ligand, forming a six-coordinated octahedral coordination geometry. Nickel/copper macrocyclic complexes were bridged by [Ni(CN)₄]^2- to construct one-dimensional chain structures in 1-4. The characterization results showed that the four complexes obeyed the Curie-Weiss law with a weak antiferromagnetic exchange coupling.