B16 tumor cells contain a warfarin sensitive vitamin K1 2,3 epoxide reductase

Biochem Biophys Res Commun. 1986 Jun 30;137(3):1015-20. doi: 10.1016/0006-291x(86)90326-8.

Abstract

Using an adapted assay that requires an enzyme aliquot that forms only 5 pmoles vitamin K, we were able to demonstrate vitamin K1 2,3 epoxide reductase activity in cultured B16 mouse melanoma cells. The enzyme uses dithiothreitol, but not NADH as a reducing cofactor and is sensitive to inhibition by warfarin (2% residual activity at 10 micrograms/ml warfarin). Incubation of B16 cells in culture with 30 micrograms/ml warfarin leads to an 45% residual reductase as compared to normally cultured B16 cells. Combined with the reported presence of vitamin K dependent carboxylase in B16 cells and the cytotoxicity of warfarin towards B16 cells this suggests an active vitamin K cycle in these melanoma cells that may be essential for survival.

MeSH terms

  • Animals
  • Cattle
  • Melanoma / enzymology*
  • Mice
  • Microsomes, Liver / enzymology
  • Mixed Function Oxygenases / antagonists & inhibitors
  • Mixed Function Oxygenases / metabolism*
  • Vitamin K / metabolism
  • Vitamin K Epoxide Reductases
  • Warfarin / pharmacology

Substances

  • Vitamin K
  • Warfarin
  • Mixed Function Oxygenases
  • Vitamin K Epoxide Reductases