Metal-organic frameworks-derived oxalate ligand modified NiCo hydroxides for enhanced electrochemical glycerol oxidation reaction

Glycerol oxidation reaction can be substituted for oxygen evolution reaction for more efficient hydrogen production due to its lower thermodynamic potential. Herein, a series of NiCo hydroxide nanosheets containing abundant Ni³⁺ species and surface ligands were synthesized by in-situ structural transformation of bimetallic organic frameworks in alkaline media for efficient glycerol oxidation reaction. It is found that the incorporation of Co ions increases the content of the Ni³⁺ species, and that the Ni/Co ratio of 1.0 lead to the optimal catalytic performance. The oxalate-modified nickel-cobalt hydroxide with the optimized Ni/Co ratio can deliver a current density of 10 mA cm^-2 at 1.26 V vs. RHE (reversible hydrogen electrode), and reaches its maximum selectivity and Faradaic efficiency at 1.30 V vs. RHE. A high selectivity of 82.9% and a Faradaic efficiency of 91.0% are achieved. The high catalytic activity can be mainly attributed to the abundant Ni³⁺ species and surface carboxyl groups.