Boron-doped graphene quantum dot/bismuth molybdate composite photocatalysts for efficient photocatalytic nitrogen fixation reactions

Bismuth molybdate (BMO) is a promising visible-driven photocatalyst and constructing heterojunctions in BMO-based materials is an effective way to enhance photocatalytic performance. In this study, boron-doped graphene quantum dots (BGQDs) were synthesized by one-step pyrolysis and carbonization, followed by the preparation of bismuth molybdate/boron-doped graphene quantum dots (BGQDs/BMO) heterojunction photocatalysts using in-situ growth method. The introduction of BGQDs significantly improved the photocatalytic nitrogen fixation activity under the irradiation of visible light and without scavengers. The highest NH₃ yield was achieved with BGQDs/BMO-10, which was 3.48 times higher than pure phase BMO. This improvement was due to the formation of Z-scheme heterojunctions between BGQDs and BMO with the synergistic mechanism of interfacial charge transport and the generation of more protons. This study provides useful guidance for enhancing the visible-light nitrogen fixation performance of BMO materials.