Post-cationic modification of a porphyrin-based conjugated microporous polymer for enhanced removal performance of bisphenol A

Shiyuan Zhou; Xiaobo Luo; Yan Zhang; Yuxi Liu; Xin Wang; Xiaoqiong Hao; Ye Zhang; Danfeng Wang; Peiyang Gu; Guangfeng Liu

doi:10.1039/d3cc05017c

Post-cationic modification of a porphyrin-based conjugated microporous polymer for enhanced removal performance of bisphenol A

Chem Commun (Camb). 2023 Dec 5;59(97):14399-14402. doi: 10.1039/d3cc05017c.

Authors

Shiyuan Zhou¹, Xiaobo Luo¹, Yan Zhang¹, Yuxi Liu¹, Xin Wang¹, Xiaoqiong Hao¹, Ye Zhang¹, Danfeng Wang¹, Peiyang Gu^{1

2}, Guangfeng Liu¹

Affiliations

¹ Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou, 213164, China. [email protected].
² Key Laboratory of Organic Synthesis of Jiangsu Province, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China.

PMID: 37974497
DOI: 10.1039/d3cc05017c

Abstract

A porphyrin-based conjugated microporous polymer photocatalyst named LDPO-2 was synthesized by a post-modification approach, which improved its hydrophilicity and visible light absorption ability. LDPO-2 achieved >99.5% removal efficiency for bisphenol A (BPA, 10 ppm) within 12 min of exposure to visible light, and the photocatalytic mechanism and potential degradation pathways were well investigated. LDPO-2 also exhibited impressive removal efficiency against BPA analogues, proving its practical applications in real-water treatment scenarios.