Room-Temperature Synthesized Iron/Cobalt Metal-Organic Framework Nanosheets with Highly Efficient Catalytic Activity toward Luminol Chemiluminescence Reaction

Yao Peng; Linying Yu; Mengting Sheng; Qian Wang; Zhiying Jin; Jianshe Huang; Xiurong Yang

doi:10.1021/acs.analchem.3c03538

Room-Temperature Synthesized Iron/Cobalt Metal-Organic Framework Nanosheets with Highly Efficient Catalytic Activity toward Luminol Chemiluminescence Reaction

Anal Chem. 2023 Dec 19;95(50):18436-18442. doi: 10.1021/acs.analchem.3c03538. Epub 2023 Dec 6.

Authors

Yao Peng¹, Linying Yu^{1

2}, Mengting Sheng¹, Qian Wang¹, Zhiying Jin^{1

2}, Jianshe Huang², Xiurong Yang^{1

2}

Affiliations

¹ Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.
² State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, P. R. China.

PMID: 38058120
DOI: 10.1021/acs.analchem.3c03538

Abstract

Two-dimensional (2D) iron/cobalt metal-organic framework nanosheets (Fe/Co-MOF NSs) were synthesized via the cooperative self-assembly reaction of Fe³⁺/Co²⁺ and terephthalic acid at room temperature. The as-prepared 2D Fe/Co-MOF NSs display superior performance in catalysis of the chemiluminescence (CL) reaction between luminol and H₂O₂. The CL spectrum, UV-vis absorption spectroscopy, radical scavenger experiments, and electron spin resonance (ESR) spectroscopy are utilized to research the possible CL mechanism of the luminol-H₂O₂-Fe/Co-MOF NSs system. All results indicate that Fe/Co-MOF NSs present outstanding peroxidase-like activity and could catalyze H₂O₂ to produce ¹O₂, O₂^·-, and ·OH, which could react rapidly with the luminol anion radical and result in strong CL. With the highly efficient CL of the luminol-H₂O₂-Fe/Co-MOF NSs system, a sensitive sensor for the detection of dopamine (DA) is developed based on the inhibitory effect of DA on the CL intensity. Good linearity over the range of 50-800 nM is achieved with a limit of detection of 20.88 nM (S/N = 3). This research demonstrates that 2D Fe/Co-MOF NSs is a highly effective catalyst for luminol CL reaction and has great application potential in the CL field.