A novel method of identifying estuary high-nutrient zones for water quality management

Coastal shallow waters are highly vulnerable to pollution, often leading to the development of intricate eutrophication zones. However, accurately determining these areas poses a significant challenge due to the complex interplay of estuarine hydrodynamics and nutrient transformation. To address such issue, a novel method was proposed to identify high-nutrient zones through calculating the continuous zonation of released tracers when their instantaneous concentrations declined to 1/e of their initial values. The method was well tested using idealized estuary models with varying shape parameters, water depths and river discharges. The results consistently revealed that the boundaries of high-nutrient zones fell within the mixed zone, characterized by salinity levels of 10- 20 psu. In Shenzhen Bay, a typical shallow bay, distinct differences were observed in the concentrations of dissolved inorganic nitrogen (DIN) and PO₄^3-. Both the 20 psu isohaline and the proposed method effectively identified the partition boundary of high DIN and PO₄^3- in 2001-2010, but only the newly proposed method demonstrated accuracy in delineating the actual high-nutrient zone during the continuous nutrient reduction period from 2010 to 2020. This study provides a practical and feasible approach that can serve as an auxiliary decision-making tool for managing estuarine water environments, and it has potential to facilitate the implementation of timely and effective measures for pollution control.