Vincazalidine A, a unique bisindole alkaloid from Catharanthus roseus

J Nat Med. 2024 Mar;78(2):382-392. doi: 10.1007/s11418-023-01775-x. Epub 2024 Feb 12.

Abstract

A new dimeric indole alkaloid, vincazalidine A consisting of an aspidosperma type and a modified iboga type with 1-azatricyclo ring system consisting of one azepane and two piperidine rings coupled with an oxazolidine ring was isolated from Catharanthus roseus, and the structure including absolute stereochemistry was elucidated on the basis of spectroscopic data as well as DP4 statistical analysis. Vincazalidine A induced G2 arrest and subsequent apoptosis in human lung carcinoma cell line, A549 cells.

Keywords: Catharanthus roseus; Apoptosis; Bisindole alkaloid; Cell proliferation; Cytotoxic activity; DP4 statistical analysis; Vincazalidine A.

MeSH terms

  • Alkaloids*
  • Antineoplastic Agents*
  • Aspidosperma* / chemistry
  • Aspidosperma* / metabolism
  • Catharanthus* / chemistry
  • Catharanthus* / metabolism
  • Humans
  • Indole Alkaloids / chemistry
  • Indole Alkaloids / pharmacology

Substances

  • Alkaloids
  • Antineoplastic Agents
  • Indole Alkaloids