Neutrophil Membrane-Camouflaged Polyprodrug Nanomedicine for Inflammation Suppression in Ischemic Stroke Therapy

Adv Mater. 2024 May;36(21):e2311803. doi: 10.1002/adma.202311803. Epub 2024 Apr 2.

Abstract

Neuroinflammation has emerged as a major concern in ischemic stroke therapy because it exacebates neurological dysfunction and suppresses neurological recovery after ischemia/reperfusion. Fingolimod hydrochloride (FTY720) is an FDA-approved anti-inflammatory drug which exhibits potential neuroprotective effects in ischemic brain parenchyma. However, delivering a sufficient amount of FTY720 through the blood-brain barrier into brain lesions without inducing severe cardiovascular side effects remains challenging. Here, a neutrophil membrane-camouflaged polyprodrug nanomedicine that can migrate into ischemic brain tissues and in situ release FTY720 in response to elevated levels of reactive oxygen species. This nanomedicine delivers 15.2-fold more FTY720 into the ischemic brain and significantly reduces the risk of cardiotoxicity and infection compared with intravenously administered free drug. In addition, single-cell RNA-sequencing analysis identifies that the nanomedicine attenuates poststroke inflammation by reprogramming microglia toward anti-inflammatory phenotypes, which is realized via modulating Cebpb-regulated activation of NLRP3 inflammasomes and secretion of CXCL2 chemokine. This study offers new insights into the design and fabrication of polyprodrug nanomedicines for effective suppression of inflammation in ischemic stroke therapy.

Keywords: anti‐inflammation; blood–brain barrier; ischemic stroke; nanomedicine; polyprodrug; scRNA‐seq.

MeSH terms

  • Animals
  • Anti-Inflammatory Agents / chemistry
  • Anti-Inflammatory Agents / pharmacology
  • Anti-Inflammatory Agents / therapeutic use
  • Cell Membrane / drug effects
  • Cell Membrane / metabolism
  • Fingolimod Hydrochloride* / chemistry
  • Fingolimod Hydrochloride* / pharmacology
  • Fingolimod Hydrochloride* / therapeutic use
  • Humans
  • Inflammation / drug therapy
  • Ischemic Stroke* / drug therapy
  • Mice
  • Microglia / drug effects
  • Microglia / metabolism
  • NLR Family, Pyrin Domain-Containing 3 Protein / metabolism
  • Nanomedicine*
  • Neuroprotective Agents / chemistry
  • Neuroprotective Agents / pharmacology
  • Neuroprotective Agents / therapeutic use
  • Neutrophils* / drug effects
  • Neutrophils* / metabolism
  • Prodrugs / chemistry
  • Prodrugs / pharmacology
  • Prodrugs / therapeutic use
  • Reactive Oxygen Species / metabolism

Substances

  • Fingolimod Hydrochloride
  • Prodrugs
  • NLR Family, Pyrin Domain-Containing 3 Protein
  • Anti-Inflammatory Agents
  • Reactive Oxygen Species
  • Neuroprotective Agents