ALOX15B controls macrophage cholesterol homeostasis via lipid peroxidation, ERK1/2 and SREBP2

Redox Biol. 2024 Jun:72:103149. doi: 10.1016/j.redox.2024.103149. Epub 2024 Apr 3.

Abstract

Macrophage cholesterol homeostasis is crucial for health and disease and has been linked to the lipid-peroxidizing enzyme arachidonate 15-lipoxygenase type B (ALOX15B), albeit molecular mechanisms remain obscure. We performed global transcriptome and immunofluorescence analysis in ALOX15B-silenced primary human macrophages and observed a reduction of nuclear sterol regulatory element-binding protein (SREBP) 2, the master transcription factor of cellular cholesterol biosynthesis. Consequently, SREBP2-target gene expression was reduced as were the sterol biosynthetic intermediates desmosterol and lathosterol as well as 25- and 27-hydroxycholesterol. Mechanistically, suppression of ALOX15B reduced lipid peroxidation in primary human macrophages and thereby attenuated activation of mitogen-activated protein kinase ERK1/2, which lowered SREBP2 abundance and activity. Low nuclear SREBP2 rendered both, ALOX15B-silenced and ERK1/2-inhibited macrophages refractory to SREBP2 activation upon blocking the NPC intracellular cholesterol transporter 1. These studies suggest a regulatory mechanism controlling macrophage cholesterol homeostasis based on ALOX15B-mediated lipid peroxidation and concomitant ERK1/2 activation.

Keywords: 15-LO2; Arachidonate 15-lipoxygenase type B; Lipid peroxidation; MAPK; Reactive oxygen species; Sterol regulatory element-binding protein 2.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Arachidonate 15-Lipoxygenase* / genetics
  • Arachidonate 15-Lipoxygenase* / metabolism
  • Cholesterol* / metabolism
  • Gene Expression Regulation
  • Homeostasis*
  • Humans
  • Lipid Peroxidation*
  • MAP Kinase Signaling System
  • Macrophages* / metabolism
  • Mitogen-Activated Protein Kinase 1 / genetics
  • Mitogen-Activated Protein Kinase 1 / metabolism
  • Mitogen-Activated Protein Kinase 3 / genetics
  • Mitogen-Activated Protein Kinase 3 / metabolism
  • Sterol Regulatory Element Binding Protein 2* / genetics
  • Sterol Regulatory Element Binding Protein 2* / metabolism

Substances

  • Sterol Regulatory Element Binding Protein 2
  • Cholesterol
  • Arachidonate 15-Lipoxygenase
  • SREBF2 protein, human
  • ALOX15B protein, human
  • Mitogen-Activated Protein Kinase 3
  • Mitogen-Activated Protein Kinase 1
  • MAPK3 protein, human
  • MAPK1 protein, human