Nitrogen-doped carbon quantum dots as dual mode fluorescence sensors for the determination of food colorant quinoline yellow

Spectrochim Acta A Mol Biomol Spectrosc. 2024 Jul 5:315:124285. doi: 10.1016/j.saa.2024.124285. Epub 2024 Apr 12.

Abstract

Quinoline yellow (QY), as a food coloring agent, will consume a large number of detoxifying substances in the body after being ingested by the human body, interfering with the normal metabolic functions of the human body, and may cause allergies, diarrhea and other symptoms, as well as a certain degree of carcinogenicity, posing a great threat to human health. As a result, it is critical to develop a fast, sensitive, and effective approach to determining quinoline yellow in food. In this study, carbon dots (N-CQDs) with high fluorescence quantum yield were prepared and used to determine the QY content using the dual mode of internal filtering effect and fluorescence emission shift detection. Both methods showed good linearity in the range of QY concentration of 0.3-3.2 μM, and the detection limits were classified as 2.6 nM and 0.18 μM. In addition, in order to achieve visual detection of QY, fluorescent test strips were constructed using the carbon dots and non-fluorescent qualitative filter paper to make the detection of QY more convenient. This probe presents a novel way for detecting quinoline yellow in food analysis.

Keywords: Dual mode; Fluorescence emission shift method; Fluorescent sensor; Fluorescent test strip; Quinoline yellow.

MeSH terms

  • Carbon* / chemistry
  • Fluorescent Dyes / chemistry
  • Food Coloring Agents / analysis
  • Limit of Detection
  • Nitrogen* / chemistry
  • Quantum Dots* / chemistry
  • Quinolines* / chemistry
  • Spectrometry, Fluorescence* / methods

Substances

  • Carbon
  • Quinolines
  • quinoline yellow
  • Nitrogen
  • Food Coloring Agents
  • Fluorescent Dyes