Influence of Water Hardness and Complexing Agents on Electrochemical Hydrogen Peroxide Generation

Recently, many studies have been published regarding electrochemical oxygen reduction reaction for generating hydrogen peroxide (H₂O₂) using gas diffusion electrodes (GDEs) for various applications. Sodium salts solved in deionized water were usually used as supporting electrolytes. In technical applications, however, tap water-based electrolytes with hardeners are particularly relevant and have only been considered in a few studies to date. In this work, we investigated the influence of hardeners on H₂O₂-generation at 150 mA cm^-2 and were able to show that scaling occurs predominantly on the GDE-surface and not in its pore structure. With the novel method in electrochemical synthesis by using complexing agents to bind hardeners, we were able to significantly reduce the scaling. Even after 10 h of operation, the reactor still achieves a faradaic efficiency (FE) of above 70 % (>67 mg h^-1 cm^-2), comparable to the experiments without hardeners and complexing agents in the electrolyte. Furthermore, we demonstrate that the complexing agents are not electrochemically converted at the carbon-based GDE and behave inertly. If the cell is operated with complexing agents and rinsed with acidic liquid (anolyte) between batches, scaling can be completely avoided.