A flexible electrochemical sensor for bisphenol A detection based on photoinitiated molecular imprinting on CdS functionalized carbon felt

Long-term and excessive exposure to bisphenol A (BPA) has an extremely detrimental effect on human health and ecological system. Hence, there is an urgent need to develop a sensitive and selective sensor for precisely monitoring BPA levels. In this work, a flexible and tailor-made electrochemical sensor for BPA has been fabricated based on in situ photopolymerization of molecular imprinting on cadmium sulfide (CdS) modified carbon felt (MIP@CdS-CF). It is worth nothing that CdS acts as a photocatalyst to enhance the capacity of photopolymerization, accordingly upgrading imprinting efficiency. Meanwhile, carbon felt (CF) exhibits attractive merits in term of superior electrical conductivity, enlarged electrochemical active areas and unique flexibility. Consequently, the novel MIP@CdS-CF electrochemical sensor shows superior sensitivity, high selectivity, extraordinary reproducibility and stability to detect BPA. The detection limit is 1.5 nM, which is lower than those of previously reported electrochemical sensors for the detection of BPA. More importantly, this newly developed electrochemical sensor can be utilized for detecting BPA in plastic bottles with satisfactory results.