Enhanced label-free detection of proteins on Au nanoparticle micropatterns for surface-enhanced infrared absorption spectroscopy

Chem Commun (Camb). 2024 Jul 9;60(56):7212-7215. doi: 10.1039/d4cc01320d.

Abstract

A label-free one-step lithographically masked deposition technique was implemented for the fabrication of gold nanoparticle (Au NP) micropatterns. These micropatterns serve as active substrates for surface-enhanced infrared absorption spectroscopy (SEIRAS) and exhibit a substantial increase in the IR signal upon adsorption of multiple proteins compared to untreated surfaces. Micro-FTIR chemical imaging was conducted to evaluate the efficacy of Au NP micropatterns as singular enhancers for SEIRAS across diverse IR-active substrates demonstrating a promising application for the detection of proteins at low concentrations within biological fluids.

MeSH terms

  • Adsorption
  • Gold* / chemistry
  • Metal Nanoparticles* / chemistry
  • Proteins / analysis
  • Proteins / chemistry
  • Spectroscopy, Fourier Transform Infrared
  • Surface Properties*

Substances

  • Gold
  • Proteins