Fast-Charging Anode Materials for Sodium-Ion Batteries

Adv Mater. 2024 Aug;36(35):e2404574. doi: 10.1002/adma.202404574. Epub 2024 Jul 4.

Abstract

Sodium-ion batteries (SIBs) have undergone rapid development as a complementary technology to lithium-ion batteries due to abundant sodium resources. However, the extended charging time and low energy density pose a significant challenge to the widespread use of SIBs in electric vehicles. To overcome this hurdle, there is considerable focus on developing fast-charging anode materials with rapid Na⁺ diffusion and superior reaction kinetics. Here, the key factors that limit the fast charging of anode materials are examined, which provides a comprehensive overview of the major advances and fast-charging characteristics across various anode materials. Specifically, it systematically dissects considerations to enhance the rate performance of anode materials, encompassing aspects such as porous engineering, electrolyte desolvation strategies, electrode/electrolyte interphase, electronic conductivity/ion diffusivity, and pseudocapacitive ion storage. Finally, the direction and prospects for developing fast-charging anode materials of SIBs are also proposed, aiming to provide a valuable reference for the further advancement of high-power SIBs.

Keywords: anode materials; electrolyte; fast charging; sodium‐ion battery; solid electrolyte interphase.

Publication types

  • Review