Preparation of Radiolabeled Zolbetuximab Targeting CLDN18.2 and Its Preliminary Evaluation for Potential Clinical Applications

Mol Pharm. 2024 Aug 5;21(8):3838-3847. doi: 10.1021/acs.molpharmaceut.4c00122. Epub 2024 Jul 1.

Abstract

Claudin18.2 (CLDN18.2), due to its high expression in various gastric cancer tissues, is considered an optimal target for antitumor drug molecules. In this study, we obtained the labeled compounds of [125I]I-zolbetuximab using the Iodogen method. Under the optimum labeling conditions, the molar activity of [125I]I-zolbetuximab was 1.75 × 102 GBq/μmol, and the labeling efficiency was more than 99%. The labeled compounds exhibited excellent in vitro stability in both phosphate buffer saline (PBS, pH = 7.4) and fetal bovine serum systems (FBS) (radiochemical purity >90% at 72 h). The uptake percentage of [125I]I-zolbetuximab in MKN45-CLDN18.2 cells is 24.69 ± 0.84% after 6 h. The saturation binding assay and specificity assay further demonstrated the high specificity of [125I]I-zolbetuximab for CLDN18.2. The long retention at the tumor site and rapid metabolic clearance at other organ sites of [125I]I-zolbetuximab were observed in small-animal SPECT-CT imaging. The same trend was also observed in the biodistribution study. Due to the excellent targeting ability of zolbetuximab for CLDN18.2, [125I]I-zolbetuximab exhibits strong specific binding and retention with cells and tumors highly expressing CLDN18.2. However, the balance between mAb's longer cycle time in vivo and targeting binding and retention ability should be intensively considered for using this kind of radiopharmaceutical in the diagnosis and treatment of CLDN18.2-positive gastric cancer.

Keywords: 125I; CLDN18.2; biological evaluation; gastric cancer; zolbetuximab.

MeSH terms

  • Animals
  • Antibodies, Monoclonal / chemistry
  • Antibodies, Monoclonal / pharmacokinetics
  • Cell Line, Tumor
  • Claudins* / metabolism
  • Female
  • Humans
  • Iodine Radioisotopes
  • Male
  • Mice
  • Mice, Inbred BALB C
  • Mice, Nude
  • Radiopharmaceuticals / chemistry
  • Radiopharmaceuticals / pharmacokinetics
  • Rats
  • Stomach Neoplasms / diagnostic imaging
  • Stomach Neoplasms / drug therapy
  • Stomach Neoplasms / metabolism
  • Tissue Distribution
  • Xenograft Model Antitumor Assays

Substances

  • CLDN18 protein, human
  • Claudins
  • Iodine Radioisotopes
  • Radiopharmaceuticals
  • Antibodies, Monoclonal
  • Iodine-125