Ultrafast and highly sensitive detection of SARS-CoV-2 spike protein by field-effect transistor graphene-based biosensors

Nanotechnology. 2024 Aug 2;35(42). doi: 10.1088/1361-6528/ad67e8.

Abstract

The severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), etiological agent for the coronavirus disease 2019 (COVID-19), has resulted in over 775 million global infections. Early diagnosis remains pivotal for effective epidemiological surveillance despite the availability of vaccines. Antigen-based assays are advantageous for early COVID-19 detection due to their simplicity, cost-effectiveness, and suitability for point-of-care testing (PoCT). This study introduces a graphene field-effect transistor-based biosensor designed for high sensitivity and rapid response to the SARS-CoV-2 spike protein. By functionalizing graphene with monoclonal antibodies and applying short-duration gate voltage pulses, we achieve selective detection of the viral spike protein in human serum within 100 µs and at concentrations as low as 1 fg ml-1, equivalent to 8 antigen molecules perµl of blood. Furthermore, the biosensor estimates spike protein concentrations in serum from COVID-19 patients. Our platform demonstrates potential for next-generation PoCT antigen assays, promising fast and sensitive diagnostics for COVID-19 and other infectious diseases.

Keywords: COVID-19; SARS-CoV-2; biosensor; field-effect transistor; graphene; monoclonal antibody.

MeSH terms

  • Antibodies, Monoclonal / chemistry
  • Antibodies, Monoclonal / immunology
  • Biosensing Techniques* / instrumentation
  • Biosensing Techniques* / methods
  • COVID-19* / blood
  • COVID-19* / diagnosis
  • COVID-19* / virology
  • Graphite* / chemistry
  • Humans
  • SARS-CoV-2* / immunology
  • SARS-CoV-2* / isolation & purification
  • Sensitivity and Specificity
  • Spike Glycoprotein, Coronavirus* / analysis
  • Spike Glycoprotein, Coronavirus* / immunology
  • Transistors, Electronic*

Substances

  • Spike Glycoprotein, Coronavirus
  • Graphite
  • spike protein, SARS-CoV-2
  • Antibodies, Monoclonal