Investigating Enhanced Microwave Absorption of CNTs@Nd0.15-BaM/PE Plate via Low-Temperature Sintering and High-Energy Ball Milling

Materials (Basel). 2024 Jul 11;17(14):3433. doi: 10.3390/ma17143433.

Abstract

Composite plates comprising a blend of rare earth neodymium-(Nd) doped M-type barium ferrite (BaM) with CNTs (carbon nanotubes) and polyethylene WERE synthesized through a self-propagating reaction and hot-pressing treatment. The plates' microscopic characteristics were analyzed utilizing X-ray diffraction (XRD), Fourier transform infrared spectrophotometry (FTIR), thermo-gravimetric analysis (TGA), Raman, and scanning electron microscopy (SEM) analytical techniques. Their microwave absorption performance within the frequency range of 8.2 to 18 GHz was assessed using a vector network analyzer. It showed that CNTs formed a conductive network on the surface of the Nd-BaM absorber, significantly enhancing absorption performance and widening the absorption bandwidth. Furthermore, dielectric polarization relaxation was investigated using the Debye theory, analyzing the Cole-Cole semicircle. It was observed that the sample exhibiting the best absorbing performance displayed the most semicircles, indicating that the dielectric polarization relaxation phenomenon can increase the dielectric relaxation loss of the sample. These findings provide valuable data support for the lightweight preparation of BaM-based absorbing materials.

Keywords: CNTs; PE; barium ferrite; microwave absorption; neodymium-doped.

Grants and funding

This work was supported by the National Natural Science Foundation of China (Grant # 52071329), the S&T Innovation 2025 Major Special Program of Ningbo (Grant # 2020Z095), the Youth Innovation Promotion Association of the Chinese Academy of Sciences, China (Grant # 2020299), the 14th Five-Year Civil Space Pre-Research Project, China (No. D020502), and the Key Research and Development Program of Ningbo, China (Grant # 2023Z195).