Stereuins A-F: Isopentenyl benzene congeners with antibacterial and neurotrophic activities from Stereum hirsutum HFG27

Phytochemistry. 2024 Dec:228:114253. doi: 10.1016/j.phytochem.2024.114253. Epub 2024 Aug 20.

Abstract

Cultivation and extraction of the fungus Stereum hirsutum (Willd.) Pers. yielded 12 isopentenyl benzene derivatives, including six previously undescribed derivatives, named stereuins A-F. Their structures were established based on NMR and mass spectroscopy analyses, supplemented by comparison with previously reported data. Stereuins A-C are unique benzoate derivatives containing fatty acid subunits. Stereuins D and E feature a valylene group and a 6/6/6 ring system. In vitro, stereuin A significantly promoted neurite outgrowth. Several compounds exhibited antibacterial activity against Staphylococcus aureus. Stereuin F has an IC50 value of 5.2 μg/mL against S. aureus, comparable to the positive control, penicillin G sodium (1.4 μg/mL).

Keywords: Antibacterial activity; Benzoate derivatives; Chemical investigation; Neurite outgrowth-promoting activity; Stereaceae; Stereum hirsutum (willd.) pers..

MeSH terms

  • Animals
  • Anti-Bacterial Agents* / chemistry
  • Anti-Bacterial Agents* / isolation & purification
  • Anti-Bacterial Agents* / pharmacology
  • Basidiomycota / chemistry
  • Benzene Derivatives / chemistry
  • Benzene Derivatives / isolation & purification
  • Benzene Derivatives / pharmacology
  • Dose-Response Relationship, Drug
  • Microbial Sensitivity Tests*
  • Molecular Structure
  • Neuronal Outgrowth / drug effects
  • Rats
  • Staphylococcus aureus* / drug effects
  • Structure-Activity Relationship

Substances

  • Anti-Bacterial Agents
  • Benzene Derivatives