Sea surface carbon dioxide during early summer at the Tuandao nearshore time series site

Mar Environ Res. 2024 Oct:201:106699. doi: 10.1016/j.marenvres.2024.106699. Epub 2024 Aug 18.

Abstract

To investigate air-sea CO2 flux at the Qingdao nearshore site and its temporal variations, a high-resolution continuous observation of surface carbon dioxide partial pressure (pCO2) was carried out at Zhongyuan Pier near Tuandao from May 25 to July 8, 2019. It was observed that during this period, surface pCO2 varied between ∼490 and ∼690 μatm, mainly associated with sea surface temperature. Surface pCO2 also displayed substantial diurnal variations, with an average amplitude of 64 ± 21 μatm, largely dominated by biological activities. During the observational period, this site acted as a source of atmospheric CO2, releasing 361 mmol CO2 m-2. The notable diurnal variations in air-sea CO2 flux, such as the observed average amplitude of 10.9 mmol m-2 d-1 in this study, pose a challenge for accurately estimating the air-sea CO2 flux in coastal regions without high-resolution observations.

Keywords: Air-sea CO(2) flux; Carbon dioxide partial pressure; Coastal waters; Diurnal variation.

MeSH terms

  • Atmosphere / chemistry
  • Carbon Dioxide* / analysis
  • China
  • Environmental Monitoring*
  • Oceans and Seas
  • Seasons*
  • Seawater* / chemistry
  • Temperature

Substances

  • Carbon Dioxide