Chitosan-blended membranes for heavy metal removal from aqueous systems: A review of synthesis, separation mechanism, and performance

Int J Biol Macromol. 2024 Nov;279(Pt 2):134996. doi: 10.1016/j.ijbiomac.2024.134996. Epub 2024 Aug 23.

Abstract

The environmental pollution caused by heavy metal ions has become a serious global environmental issue. Heavy metal contaminants released from industrial effluents, agricultural runoff, and human activities, can enter into water resources. The toxicity of these heavy metal ions even at trace concentrations presents a substantial hazard to both aquatic systems and human well-being. The membrane separation processes have become more promising sustainable techniques for the separation of metal ions from the effluent. The research efforts have been concentrated on improving the synthesis of membranes and membrane materials to facilitate the sustainable separation of heavy metals. The application of chitosan in the fabrication of membranes is getting more attention. Chitosan, a natural polysaccharide derived from chitin, is abundant in nature and has active hydroxyl and amino groups suitable for the separation of heavy metal ions. It exhibits excellent chelating tendency, biocompatibility, and biodegradability. The functionalization of chitosan to improve its mechanical strength, chemical stability, and antifouling properties has become an ongoing area of research. This review examines the synthesis and efficient applications of chitosan blended membranes. The review concludes by outlining the current challenges and proposing future research prospects to enhance the applicability of chitosan-blended membranes in environmental remediation.

Keywords: Chitosan; Environmental remediation; Heavy metal removal; Hybrid membrane; Membrane filtration; Membrane synthesis.

Publication types

  • Review

MeSH terms

  • Chitosan* / chemistry
  • Humans
  • Membranes, Artificial*
  • Metals, Heavy* / chemistry
  • Metals, Heavy* / isolation & purification
  • Water Pollutants, Chemical* / chemistry
  • Water Pollutants, Chemical* / isolation & purification
  • Water Purification* / methods

Substances

  • Chitosan
  • Metals, Heavy
  • Membranes, Artificial
  • Water Pollutants, Chemical