Methylene blue sorption performance of lignocellulosic peach kernel shells modified with cellulose derivative chitosan as a new bioadsorbent

In this study, adsorption isotherms (Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich) and thermodynamic properties of cationic methylene blue (MB) dye adsorption onto chitosan-coated peach kernel shell waste (CTS-PKSh) from wastewater were investigated. CTS was cross-linked with citric acid (CA) and glutaraldehyde (GA). The adsorbents were characterized by FE-SEM/EDS, FTIR, and particle size distribution. MB adsorption behavior onto the biosorbents was investigated concerning parameters such as adsorbent dosage (0.8-8 g/L), time (0-540 min), pH (3-10), initial dye concentration (50-700 mg/L), and temperature (25-55 °C). The Langmiur q_max and experimentally q_e MB adsorption capacities of the new adsorbents were found to be 227.27 and 201 mg/g for CA cross-linked CTS-PKSh (CA@CTS-PKSh) and 111.12 and 96.5 mg/g for GA cross-linked CTS-PKSh (GA@CTS-PKSh), respectively. The results of thermodynamic analysis showed that adsorption was feasible, exothermic, and spontaneous. According to adsorption and recyclability results, CA@CTS-PKSh was more effective for MB removal at a 2 g/L adsorbent dose for an initial dye concentration of 100 mg/L, 25 ± 1 °C, contact time 60 min, and pH 7.