Electrospinning Recombinant Spider Silk Fibroin-Reinforced PLGA Membranes: A Biocompatible Scaffold for Wound Healing Applications

ACS Biomater Sci Eng. 2024 Nov 11;10(11):7144-7154. doi: 10.1021/acsbiomaterials.4c01605. Epub 2024 Oct 22.

Abstract

Polylactide-polyglycolide (PLGA) is one of the most attractive polymeric biomaterials used to fabricate medical devices for drug delivery and tissue engineering applications. Nevertheless, the utilization of PLGA in load-bearing applications is restricted due to its inadequate mechanical properties. This study examines the potential of recombinant silk fibroin (eADF4), a readily producible biomaterial, as a reinforcing agent for PLGA. The PLGA/eADF4 composite membranes were developed by using the process of electrospinning. The spinnability of the electrospinning solutions and the physicochemical, mechanical, and thermal properties of the composite membranes were characterized. The addition of eADF4 increased the viscosity of the electrospinning solutions and enhanced both the mechanical characteristics and the thermal stability of the composites. This study demonstrates that PLGA membranes reinforced with recombinant spider silk fibroin are noncytotoxic, significantly enhance cell migration and wound closure, and do not trigger an inflammatory response, making them ideal candidates for advanced wound healing applications.

Keywords: electrospinning; mechanical properties; polylactide−polyglycolide; recombinant spider silk fibroin; reinforcement; wound healing.

MeSH terms

  • Animals
  • Biocompatible Materials* / chemistry
  • Biocompatible Materials* / pharmacology
  • Cell Movement / drug effects
  • Fibroins* / chemistry
  • Fibroins* / pharmacology
  • Humans
  • Lactic Acid / chemistry
  • Lactic Acid / pharmacology
  • Membranes, Artificial
  • Polyglycolic Acid / chemistry
  • Polylactic Acid-Polyglycolic Acid Copolymer* / chemistry
  • Recombinant Proteins* / chemistry
  • Recombinant Proteins* / pharmacology
  • Spiders
  • Tissue Scaffolds* / chemistry
  • Wound Healing* / drug effects

Substances

  • Fibroins
  • Polylactic Acid-Polyglycolic Acid Copolymer
  • Biocompatible Materials
  • Recombinant Proteins
  • Polyglycolic Acid
  • Lactic Acid
  • Membranes, Artificial