Palladium-catalyzed C-H bond activation and decarboxylation for the assembly of indolo[1,2- f]phenanthridine

Org Biomol Chem. 2024 Oct 24. doi: 10.1039/d4ob01383b. Online ahead of print.

Abstract

A direct and convenient strategy for the assembly of indolo[1,2-f]phenanthridine via a Pd-catalyzed tandem cyclization reaction is presented. The current strategy delivers a range of indolo[1,2-f]phenanthridine derivatives by utilizing readily available 1-(2-iodophenyl)-1H-indole and commercially available o-bromobenzoic acids as the starting materials. The reaction features the formation of two C-C bonds through Pd-catalyzed C-H bond activation and decarboxylation.