Bone Healing via Carvacrol and Curcumin Nanoparticle on 3D Printed Scaffolds

Small. 2024 Dec;20(50):e2405642. doi: 10.1002/smll.202405642. Epub 2024 Oct 27.

Abstract

Carvacrol is a potent antimicrobial and anti-inflammatory agent, while curcumin possesses antioxidant, anti-inflammatory, and anticancer properties. These phytochemicals have poor solubility, bioavailability, and stability in their free form. Nanoencapsulation can reduce these limitations with enhanced translational capability. Integrating nanocarriers with 3D-printed calcium phosphate (CaP) scaffolds presents a novel strategy for bone regeneration. Carvacrol and curcumin-loaded nanoparticles (CC-NP) synthesized with melt emulsification produced negatively charged, monodispersed particles with a hydrodynamic diameter of ≈127 nm. Their release from the scaffold shows a biphasic release under physiological and acidic conditions. At pH 5.0, the CC-NP exhibits a 53% release of curcumin and nearly 100% release of carvacrol, compared to 19% and 36% from their respective drug solutions. At pH 7.4, ≈40% of curcumin and 76% of carvacrol releases, highlighting their pH-sensitive release mechanism. In vitro studies demonstrate a 1.4-fold increase in osteoblast cell viability with CC-NP treatment. CC-NP exhibit cytotoxic effects against osteosarcoma cells, reducing cell viability by ≈2.9-fold. The antibacterial efficacy of CC-NP evaluated against Staphylococcus aureus (SA) and Pseudomonas aeruginosa (PA) exhibiting 98% antibacterial efficacy. This approach enhances therapeutic outcomes and minimizes the potential side effects associated with conventional treatments, paving the way for innovative applications in regenerative medicine.

Keywords: 3D printing; bone tissue engineering; carvacrol; curcumin; lipid nanoparticles.

MeSH terms

  • Bone Regeneration / drug effects
  • Cell Survival / drug effects
  • Curcumin* / chemistry
  • Curcumin* / pharmacology
  • Cymenes* / chemistry
  • Cymenes* / pharmacology
  • Humans
  • Monoterpenes / chemistry
  • Monoterpenes / pharmacology
  • Nanoparticles* / chemistry
  • Osteoblasts / cytology
  • Osteoblasts / drug effects
  • Printing, Three-Dimensional*
  • Staphylococcus aureus / drug effects
  • Tissue Scaffolds* / chemistry

Substances

  • carvacrol
  • Cymenes
  • Curcumin
  • Monoterpenes