Efficacy of Chitosan-N-Arginine Chitosomes in mRNA Delivery and Cell Viability Enhancement

ACS Appl Bio Mater. 2024 Dec 16;7(12):8261-8271. doi: 10.1021/acsabm.4c00983. Epub 2024 Nov 18.

Abstract

Cationic lipid-based carriers are recognized for their ability to complex with mRNA and effectively deliver the mRNA for vaccination and therapeutic purposes. However, the significant cytotoxicity of these carriers often restricts their practical application. In the present study, polymer-lipid hybrid nanoparticles, termed chitosomes, incorporating chitosan-N-arginine (CSA) with the DOTAP cationic lipid and the DOPE helper lipid, were synthesized and evaluated. The addition of CSA to the lipid formulations improved their physicochemical stability and enhanced mRNA complexation, resulting in high transfection rates in the HeLa and HEK293T cell lines. However, the transfection efficiency was low in the NIH-3T3 cell line, indicating a cell type-specific response to chitosomes. Importantly, CSA significantly reduced the cytotoxicity typically associated with DOTAP. Overall, the present study indicated that optimizing the ratio of CSA to DOTAP is crucial for developing mRNA nanocarriers to achieve high transfection efficiency and reduce cytotoxicity across different cell lines.

Keywords: Chitosan; Chitosome; Gene delivery; Hybrid systems; Lipids; mRNA delivery.

MeSH terms

  • Animals
  • Arginine* / chemistry
  • Arginine* / pharmacology
  • Biocompatible Materials* / chemical synthesis
  • Biocompatible Materials* / chemistry
  • Biocompatible Materials* / pharmacology
  • Cell Survival* / drug effects
  • Chitosan* / chemistry
  • HEK293 Cells
  • HeLa Cells
  • Humans
  • Materials Testing*
  • Mice
  • Molecular Structure
  • NIH 3T3 Cells
  • Nanoparticles / chemistry
  • Particle Size*
  • RNA, Messenger* / metabolism
  • Transfection

Substances

  • Chitosan
  • RNA, Messenger
  • Arginine
  • Biocompatible Materials