Colorimetric and electrochemical analysis of DNAzyme-LAMP amplicons for the detection of Escherichia coli in food matrices

Sci Rep. 2024 Nov 22;14(1):28942. doi: 10.1038/s41598-024-80392-4.

Abstract

Foodborne bacteria like Escherichia coli threaten global food security, necessitating affordable, on-site detection methods, especially in resource-limited settings. This study optimized loop-mediated isothermal amplification (LAMP) integrated with peroxidase-mimicking G-quadruplex DNA structures (DNAzyme), termed DNAzyme-LAMP which was designed to incorporate two different catalytic DNAzymes per amplification unit, enabling colorimetric detection of E. coli in leafy vegetables and milk samples. Additionally, we introduce a novel electrochemical method that enhances analytical sensitivity. The optimized DNAzyme-LAMP achieved a detection limit below 6.3 CFU per reaction or 0.1 aM gene copies. This system lays the groundwork for the development of on-site biosensors and can be adapted for detecting other foodborne pathogens.

Keywords: E. coli; Electrochemical sensing; Food safety; G-quadruplex DNAzyme; Loop mediated isothermal amplification (LAMP); Magnetic beads.

MeSH terms

  • Animals
  • Biosensing Techniques / methods
  • Colorimetry* / methods
  • DNA, Catalytic* / genetics
  • DNA, Catalytic* / metabolism
  • Electrochemical Techniques* / methods
  • Escherichia coli* / genetics
  • Escherichia coli* / isolation & purification
  • Food Microbiology* / methods
  • G-Quadruplexes
  • Limit of Detection
  • Milk / microbiology
  • Molecular Diagnostic Techniques
  • Nucleic Acid Amplification Techniques* / methods
  • Vegetables / microbiology

Substances

  • DNA, Catalytic

Supplementary concepts

  • LAMP assay

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