Resin infiltrant with antibacterial activity: effects of incorporation of DMAHDM monomer and NACP on physical and antimicrobial properties

J Appl Oral Sci. 2024 Dec 2:32:e20240263. doi: 10.1590/1678-7757-2024-0263. eCollection 2024.

Abstract

Objectives: Considering the fact that resin infiltrants lack antibacterial activity, this study assessed the influence of the quaternary ammonium monomer dimethylaminohexadecyl methacrylate (DMAHDM) and amorphous calcium phosphate nanoparticles (NACP) on the physical and antibacterial properties of an experimental resin infiltrant (ERI).

Methodology: The following groups were established: ERI (75/25 wt.% TEGDMA/BISEMA), ERI + 2.5% DMAHDM (2.5DM), ERI + 5% DMAHDM (5DM), ERI + 2% NACP (NACP), ERI + 2.5% DMAHDM + 2% NACP (2.5DM_NACP), ERI + 5% DMAHDM + 2% NACP (5DM_NACP), and Icon® (IC), a commercial resin infiltrant. Degree of conversion (DC; n=4), sorption and solubility (SO/SOL; n=8), and contact angle (CA; n=10) tests were conducted. Biofilm biomass (BB; n=6) and bacterial metabolism (BM; n=8) were evaluated after Streptococcus mutans (UA159) cultivation for 48 h on material samples. Data were evaluated by one-way ANOVA and Tukey or Games-Howell post hoc tests (α=0.05).

Results: IC exhibited the highest DC, with no difference from 2.5DM and 5DM. IC showed the lowest CA. IC had the lowest SO, followed by ERI, which had the lowest SOL, with no difference from IC. 5DM_NACP showed the lowest biofilm biomass, similar to 2.5DM and 5DM. Resin infiltrants containing DMAHDM showed reduced bacterial metabolism.

Conclusions: DMAHDM, with or without NACP, demonstrated significant antibacterial activity, while NACP impaired DC. Both DMAHDM and NACP increased the contact angle, sorption, and solubility of the resin infiltrant, which may affect the material's clinical performance.

Publication types

  • Evaluation Study

MeSH terms

  • Analysis of Variance
  • Anti-Bacterial Agents* / chemistry
  • Anti-Bacterial Agents* / pharmacology
  • Biofilms* / drug effects
  • Calcium Phosphates* / chemistry
  • Calcium Phosphates* / pharmacology
  • Composite Resins / chemistry
  • Composite Resins / pharmacology
  • Materials Testing*
  • Methacrylates* / chemistry
  • Methacrylates* / pharmacology
  • Microbial Sensitivity Tests
  • Microscopy, Electron, Scanning
  • Nanoparticles / chemistry
  • Polyethylene Glycols / chemistry
  • Polyethylene Glycols / pharmacology
  • Polymethacrylic Acids / chemistry
  • Polymethacrylic Acids / pharmacology
  • Quaternary Ammonium Compounds / chemistry
  • Quaternary Ammonium Compounds / pharmacology
  • Reference Values
  • Reproducibility of Results
  • Solubility
  • Statistics, Nonparametric
  • Streptococcus mutans* / drug effects
  • Surface Properties
  • Time Factors

Substances

  • Methacrylates
  • Anti-Bacterial Agents
  • Calcium Phosphates
  • amorphous calcium phosphate
  • Polymethacrylic Acids
  • Composite Resins
  • triethylene glycol dimethacrylate
  • Quaternary Ammonium Compounds
  • Polyethylene Glycols