Concise total synthesis of (±)-applanatumol Y

Org Biomol Chem. 2024 Dec 11. doi: 10.1039/d4ob01763c. Online ahead of print.

Abstract

Total synthesis of (±)-applanatumol Y was achieved in 5 steps, featuring a cascade annulation including Michael addition, aldol condensation, and oxy-Michael addition reactions, all promoted by DBU. This approach offers a streamlined and cost-effective route for constructing complex tricyclic frameworks under mild and metal-free conditions.