Optically active cofacial ABCD-Pt(II)-porphyrin dimer exhibits bright circularly polarized phosphorescence

Chem Commun (Camb). 2024 Dec 17. doi: 10.1039/d4cc05684a. Online ahead of print.

Abstract

Synthesis of an intrinsically chiral cofacial ABCD-Pt(II)-porphyrin (Por) dimer was achieved by the simple Pt-templated synthesis of Por, followed by Suzuki-Miyaura cross-coupling. The isolated enantiomers exhibited bright red circularly polarized phosphorescence with a BCPP value above 101 M-1 cm-1.