Three-dimensionally structured MoS₂@biochar breaks through the bottleneck in antibiotic wastewater treatment: Greater efficiency and self-motivated oxidation pathway

Two-dimensional (2D) MoS₂ has been widely used to remove antibiotics. However, low selectivity for antibiotic pollutants, dependence on applied energy and oxidant, and secondary contamination are still the bottlenecks of this system for treating antibiotic wastewater. In this study, we proposed a three-dimensional (3D) material (3MoS₂/BMBC@MF) based on MoS₂ and biochar with melamine sponge as the backbone. Compared with the 2D material (MoS₂/BMBC), 3MoS₂/BMBC@MF performed significantly better in enrofloxacin (ENR) removal, with an increase in the removal degree from 60.8 % to 88.1 %, and acted mainly through the degradation pathway rather than relying solely on the adsorption effect. It was shown that the direct oxidation process (DOP) behind the 3D materials is the key to the self-activated oxidation pathway. The three-dimensional structure enhances the generation and transfer pathways of persistent free radicals (PFRs) and electrons, realizing a multi-dimensional activation mechanism through its unique three-dimensional network, which greatly improves the redox capacity of the material. Upon exposure to pollutants, 3MoS₂/BMBC@MF generates carbon-centered radicals of PFRs, which degrade ENR through mediated electron transfer. Coupled with the three-dimensional structure that contributes to the homogeneous dispersion of the active substances, dense steric active centers are formed in the grid skeleton by redox cycling of Mo ions to degrade antibiotics via DOP. Meanwhile, 3MoS₂/BMBC@MF possesses good recyclability and maintains high efficiency in recycling. The structural design of this material not only enhances the removal efficiency and reduces the environmental impact, but also provides new potentials and solutions for practical water treatment of antibiotic contaminants.