The rational design of multicomponent heterostructure is an effective strategy to enhance the catalytic activity of electrocatalysts for water and seawater electrolysis in alkaline conditions. Herein, MOF-derived nitrogen-doped carbon/nickel-cobalt sulfides coupled vertically aligned Rhenium disulfide (ReS2) on carbon cloth (NC-CoNi2S4@ReS2/CC) are constructed via hydrothermal and activation approaches. Experimental and theoretical analysis demonstrates that the strong interactions between multiple interfaces promote electron redistribution and facilitate water dissociation, thereby optimizing *H adsorption energy for the hydrogen evolution reaction (HER). Meanwhile, the adsorption energies of oxygenated intermediates are balanced to reduce the thermodynamic barrier for the oxygen evolution reaction (OER). Consequently, NC-CoNi2S4@ReS2/CC shows smaller overpotentials of 87 and 253 mV for HER and OER at 10 mA cm-2, with a lower Tafel slope and Rct than control samples. Superior catalytic stability is confirmed by cyclic voltammetry (CV) for 1000 cycles and CA test for 56 h. Furthermore, NC-CoNi2S4@ReS2/CC presents exceptional electrocatalytic activity in both alkaline water/seawater electrolytes. Stability assessments reveal that NC-CoNi2S4@ReS2/CC maintains a highly catalytic activity in both water and seawater, owing to the corrosion-resistant properties of the sulfur species at the interface. These findings highlight the importance of designing heterostructure electrocatalysts for clean hydrogen production.
Keywords: heterostructure; nitrogen‐doped carbon; rhenium disulfide; seawater splitting; strong interaction.
© 2024 The Author(s). Advanced Science published by Wiley‐VCH GmbH.