Comparison of microplastics heteroaggregation with MoS₂ and graphene oxide nanosheets: Dependence on the configuration and impacts on aquatic transport

Understanding the behavior and fate of microplastics (MPs) in aquatic environment is crucial for assessing their potential risks. This study investigated the heteroaggregation behaviors of MPs with representative 2D nanosheets, MoS₂ and graphene oxide (GO), under various conditions, focusing on the transport behavior of the resulting aggregates. It was found that the destabilization capabilities of 2D nanosheets are notably stronger than those of well-reported nanoparticles. More importantly, the deposition and transport of MPs are highly dependent on the configuration of the resulting aggregates. MoS₂ nanosheets conformally coat MPs, forming compact and colloidally stable complexes that completely alter the MPs' surface to the negatively charged MoS₂. The interaction resulted in high mobility and minimal deposition in environmental matrices. In contrast, GO nanosheets bridge MPs into large clusters, reducing transport and increasing deposition. This difference in aggregate configuration is attributed to the distinct interactions between the nanosheets and MPs: rigid MoS₂ nanosheets adhere via strong van der Waals forces, while GO, with oxygen functional groups on its edges and surfaces, folds and crosslinks between particles upon adsorption. These findings underscore the critical role of 2D materials in shaping the environmental fate of MPs, advancing our knowledge on the aggregation process.