Enhanced treatment of multiphase extraction wastewater from contaminated sites with Cu-Ce modified GAC three-dimensional electrodes

A three-dimensional (3D) electrode system is widely recognized as an effective technology for enhancing electrocatalytic effect. In this study, Cu-Ce modified granular activated carbon (GAC) particle electrodes were prepared using the impregnation method and applied to handle multiphase extraction wastewater. Structural and electrochemical characterization revealed that while the specific surface area of Cu-Ce/GAC decreased by 13.94%, the active area was 2.6 times greater than that of GAC. In addition, the influences of distinct impregnation concentrations, calcination temperatures, and calcination times on the performance of Cu-Ce/GAC electrodes were investigated. The results suggested the optimal preparation conditions of 15 mmol/L, 500 °C and 2 h. Under these conditions, the Cu-Ce/GAC electrode achieved a 92.39% removal of chemical oxygen demand (COD) from a multi-extract of groundwater, with an energy consumption of 13.44 kWh/(kg∙COD). The degradation efficiency improved by 62% compared to the conventional 2D system, while energy consumption decreased by 60%. The main organic pollutants in the multiple extracts, including benzene, toluene, dichloromethane, trichloromethane, were removed at rates exceeding 90% after 60 min treatment. This study yields a methodological and engineering approach for treating multiple extracts wastewater from contaminated groundwater.