Linear Enhanced 3D Nanofluid Force-Electric Conversion Device

Adv Mater. 2025 Jan 6:e2417498. doi: 10.1002/adma.202417498. Online ahead of print.

Abstract

The inherent trade-off between permeability and selectivity has constrained further improvement of passive linear force-electric conversion performance in nanofluidic pressure sensors. To overcome this limitation, a 3D nanofluidic membrane with high mechanical strength utilizing aramid nanofibers/carbon nanofiber (ANF/CNF) dual crosslinking is developed. Due to the abundant surface functional groups of CNF and the high mechanical strength of ANF, this large-scale integrated 3D nanofluidic membrane exhibits advantages of high flux, high porosity, and short ion transport path, demonstrating superior force-electric response compared to conventional 1D and 2D configurations. The enhancement mechanism of the ANF/CNF membrane is systematically investigated through experimental results and theoretical calculations. The optimized device has a sensitivity of 111 nA cm-2 kPa-1, a response/recovery time of 63/68 ms, and a stability of 45 000 cycles. This study successfully overcomes the inherent performance limitations of traditional nanofluidic membranes, offering promising potential for applications across artificial intelligence, the Internet of Things, and smart wearable devices.

Keywords: 3D nanofluid membranes; linear force‐electric conversion; permeability; pressure sensor; selectivity.