The dependence of the rate constant of the recombination reaction of CCl2 and NO2 radicals on temperature and pressure was studied. Quantum-chemical calculations were employed to characterize relevant aspects of the potential energy surface for this process. The limiting rate constants between 300 and 2000 K were analyzed using the unimolecular reactions theory. The resulting low pressure rate constant can be represented as k0 = [He] (1.4 ± 0.2) × 10-26 (T/300 K)-8.72±0.04 exp(-(1520 ± 10) K/T) cm3 molecule-1 s-1. The corresponding expressions for the high pressure limit rate constants, derived from a simplified version of the statistical adiabatic channel (SSACM) and from a SACM combined with classical trajectory calculations (SACM/CT), are (2.3 ± 1.9) × 10-11 (T/300 K)-1.01±0.39 exp(-(810 ± 80) K/T) and (8.8 ± 5.3) × 10-13 (T/300 K)0.82±0.13 cm3 molecule-1 s-1. The falloff curves were represented in terms of these limiting rate constants. Reported experimental results are well described with the present model. Our calculations indicate that the CCl2 + NO2 reaction proceeds via the stabilization of the energized CCl2NO2 adduct, and that the CCl2 + NO2 → CCl2O + NO channel becomes relevant at high temperatures.